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High Performance Duplex Stainless Steel

Duplex Steel 2205 (UNS S32205 / S31803) Pipe Fittings & Flanges Manufacturer

PED 2014/68/EU & ISO 9001 Certified. Delivering high-PREN duplex solutions for desalination, oil & gas, and chemical processing environments worldwide.

  • Dual Certified: Meeting both UNS S31803 and S32205 standards.
  • High Performance: Enhanced Nitrogen for PREN >35 and superior weldability.
  • Full Traceability: EN 10204 3.1 MTC with 100% PMI testing.
ISO 9001:2015 PED 2014/68/EU DNV Approved
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Technical specification by
Sunhyings Metallurgy Team
30+ years experience in forging and machining special alloy fittings. Expertise in heat input control for duplex welding.
Standards Compliance: ASTM A790, A815, A182, ASME B16.9, B16.5.
Data verified against NACE MR0175 / ISO 15156 for sour service applications. Values provided are typical for Sunhyings production.

1. Duplex 2205 Overview: S31803 vs S32205

Duplex 2205 is a nitrogen-enhanced duplex stainless steel consisting of approximately 50% ferrite and 50% austenite. This mixed microstructure provides a unique combination of high strength (twice that of 304/316) and excellent corrosion resistance.

While often used interchangeably, there is a distinct difference between the two common UNS designations:

  • UNS S31803: The original specification for 2205.
  • UNS S32205: The modern, "restricted chemistry" version. It requires higher minimum limits for Chromium, Molybdenum, and Nitrogen.

Sunhyings Policy: We primarily stock and manufacture Dual Certified (S31803/S32205) material. By meeting the stricter S32205 chemistry, we ensure better corrosion resistance and optimized phase balance after welding.

2. Chemical Composition & PREN Value

The addition of Nitrogen is critical for stabilising the austenite phase during welding. See how Sunhyings internal standards compare to the generic specs.

Element UNS S31803 (Min) UNS S32205 (Min) Sunhyings Typical Effect
Chromium (Cr) 21.0% 22.0% 22.5% Basic corrosion resistance.
Molybdenum (Mo) 2.5% 3.0% 3.2% Resistance to pitting & crevice corrosion.
Nitrogen (N) 0.08% 0.14% 0.17% Increases strength & pitting resistance; stabilizes austenite.
Nickel (Ni) 4.5% 4.5% 5.6% Toughness & phase balance.

PREN Formula: PREN = %Cr + 3.3(%Mo) + 16(%N)
Sunhyings guarantees a PREN ≥ 35 for our S32205 products, ensuring superior resistance to seawater pitting compared to standard S31803 (PREN ~33).

3. Manufacturing Range: Fittings & Flanges

We manufacture a complete line of pipe components in Wenzhou, covering both butt weld and forged types.

Butt Weld Fittings (ASTM A815 / ASME B16.9)

Types Elbows (45°/90°/180°, LR/SR), Tees (Equal/Reducing), Concentric & Eccentric Reducers, Stub Ends, End Caps.
Size Range 1/2" to 48" (Seamless up to 24", Welded 26"-48")
Thickness SCH 10S, SCH 40S, SCH 80S, SCH 160, XXS.

Forged Fittings & Flanges (ASTM A182)

Flanges (B16.5) Weld Neck (WN), Slip-on (SO), Blind, Socket Weld (SW), Threaded. Class 150# to 2500#.
Forged Fittings (B16.11) Socket Weld & Threaded (NPT/BSP) Elbows, Tees, Unions, Couplings. Rating: 3000#, 6000#, 9000#.

4. Mechanical Properties (Room Temp)

Duplex 2205 allows engineers to design with thinner walls due to its high yield strength, often leading to weight and cost savings compared to 316L.

Property Value (Min) Notes
Tensile Strength (Rm) ≥ 655 MPa (95 ksi) Approx. 25% higher than 316L.
Yield Strength (0.2%) ≥ 450 MPa (65 ksi) Double the strength of 316L (205 MPa).
Elongation ≥ 25% Good ductility for forming.
Hardness ≤ 290 HB / 31 HRC Compliant with NACE MR0175 limits.

5. Applications & Corrosion Performance

Why choose 2205? It solves the problem of Stress Corrosion Cracking (SCC) that plagues 304/316 in hot chloride environments.

Desalination (SWRO)

With PREN >34, 2205 is the industry standard for high-pressure piping in Reverse Osmosis plants, handling seawater where 316L would fail from pitting.

Oil & Gas (Sour Service)

Approved for use in sour environments (H2S-containing) per NACE MR0175 / ISO 15156. High resistance to sulfide stress cracking.

Chemical Processing

Excellent performance in acetic acid, formic acid, and PVC production environments. Superior abrasion resistance for slurry handling.

6. Welding & Fabrication Guide

Welding 2205 requires more technical control than 304/316 to maintain the austenite-ferrite balance.

  • Filler Metal: Always use ER2209 (over-alloyed with Ni) to promote austenite formation in the weld. Autogenous welding (without filler) is not recommended.
  • Heat Input: Strictly control between 0.5 – 2.5 kJ/mm.
    • Too low = High ferrite (loss of corrosion resistance).
    • Too high = Sigma phase precipitation (embrittlement).
  • Interpass Temperature: Maximum 150°C.
  • Shielding Gas: Ar + 1-2% N2 is recommended to compensate for nitrogen loss.

7. Quality Assurance & MTC

Trust is built on transparency. Every shipment from Sunhyings includes detailed documentation.

  • MTC: EN 10204 3.1 Certificate including chemical analysis, tensile test, hardness test, and heat treatment batch.
  • Non-Destructive Testing (NDT):
    • 100% PMI (Positive Material Identification) to prevent material mix-up.
    • Radiography (RT) or Ultrasonic (UT) for welded fittings as per ASME/ASTM.
  • Corrosion Testing: ASTM G48 Method A (Pitting test) available upon request.

8. FAQ: Duplex 2205 Questions

Q1. Is Duplex 2205 magnetic?

Yes. Unlike 304 or 316 austenitic stainless steels, Duplex 2205 has a ferromagnetic structure due to its ~50% ferrite content. It will strongly attract a magnet.

Q2. What is the maximum operating temperature for 2205?

Duplex 2205 is generally limited to 300°C (572°F) maximum. Long-term exposure above this temperature (specifically 475°C) causes "475°C embrittlement," drastically reducing toughness.

Q3. Can I use 316L filler wire to weld 2205?

No. Using 316L filler will result in a weld with much lower strength and corrosion resistance than the 2205 base metal. You must use ER2209 or E2209 filler.

9. Talk to a Sunhyings Engineer

Need a quote for S32205 Flanges or Fittings? Send us your bill of materials. We reply within 24 hours with stock availability and pricing.

Resources

  • Duplex 2205 Technical Datasheet (PDF)
  • Sunhyings ISO 9001 & PED Certificates
  • ASTM A182 / A815 Dimensional Tolerances
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